Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis
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When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part i...
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When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part i...
Read more